Improved continuous synthesis of UiO-66 enabling outstanding production rates
نویسندگان
چکیده
Optimization of the continuous synthesis UiO-66 and derivatives with extremely high space time yield using a tubular reactor.
منابع مشابه
A facile synthesis of UiO-66, UiO-67 and their derivatives.
A scalable, reproducible method of synthesizing UiO-66- and UiO-67-type MOFs, entailing the addition of HCl to the reaction mixture, has been investigated. The new protocol requires a fraction of the time of previously reported procedures, yields exceptional porosities, and works with a range of linkers.
متن کاملH2 storage in isostructural UiO-67 and UiO-66 MOFs.
The recently discovered UiO-66/67/68 class of isostructural metallorganic frameworks (MOFs) [J. H. Cavka et al. J. Am. Chem. Soc., 2008, 130, 13850] has attracted great interest because of its remarkable stability at high temperatures, high pressures and in the presence of different solvents, acids and bases [L. Valenzano et al. Chem. Mater., 2011, 23, 1700]. UiO-66 is obtained by connecting Zr...
متن کاملUtilisation of gold nanoparticles on amine-functionalised UiO-66 (NH2-UiO-66) nanocrystals for selective tandem catalytic reactions.
Colloidal deposition of gold nanoparticles (Au NPs) onto NH2-UiO-66 nanocrystals has been demonstrated with the resulting hybrid catalyst proving robust and versatile for one-pot, heterogeneous conversions involving the selective oxidation of primary alcohols in tandem with Knoevenagel condensation reactions. Within these systems, structure-property correlations have been established to confirm...
متن کاملEfficient microwave assisted synthesis of metal-organic framework UiO-66: optimization and scale up.
A highly efficient and scalable microwave assisted synthesis of zirconium-based metal-organic framework UiO-66 was developed. In order to identify the best conditions for optimizing the process, a wide range of parameters was investigated. The efficiency of the process was evaluated with the aid of four quantitative indicators. The properties of the materials prepared by microwave irradiation w...
متن کاملIsoreticular synthesis and modification of frameworks with the UiO-66 topology.
Amino, bromo, nitro, and naphthalene functionalized UiO-66 metal-organic frameworks have been synthesized through reticular chemistry. UiO-66-NH(2) is shown to be suitable for postsynthetic modification with a variety of anhydrides to generate new, functionalized frameworks.
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ژورنال
عنوان ژورنال: Reaction Chemistry and Engineering
سال: 2021
ISSN: ['2058-9883']
DOI: https://doi.org/10.1039/d0re00464b